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HDPE

Commodity $

High-density polyethylene. The workhorse semi-crystalline commodity polyolefin for chemical tanks, water pipe, cutting boards, marine construction, and any application requiring chemical resistance, low cost, and easy thermoplastic welding. Stiffer and stronger than LDPE and LLDPE but still soft compared to engineering plastics. Near-zero moisture absorption, excellent chemical resistance, FDA-compliant grades widely available. The catch is low maximum service temperature (~80°C), high thermal expansion, and surfaces that won't bond without treatment.

Service °C
75–85°C continuous (167–185°F) — softens noticeably above this
Tensile
24–32 MPa (3,500–4,600 psi) — unfilled grades; glass-filled grades reach 60–80 MPa
Density
0.93–0.97 g/cm³ (0.034 lb/in³) — floats on water
Cost
$
$1.40/lb
Trade names: Polystone G (Röchling)Densetec (Polymer Industries)King StarBoard (King Plastic, marine)Sanatec (FDA cutting-board grade)Orthoform (Curbell, O&P grade)Seaboard (Plaskolite, marine)TimberLine (woodgrain HDPE)Marlex (Chevron Phillips, raw resin)

High-density polyethylene. The workhorse semi-crystalline commodity polyolefin for chemical tanks, water pipe, cutting boards, marine construction, and any application requiring chemical resistance, low cost, and easy thermoplastic welding. Stiffer and stronger than LDPE and LLDPE but still soft compared to engineering plastics. Near-zero moisture absorption, excellent chemical resistance, FDA-compliant grades widely available. The catch is low maximum service temperature (~80°C), high thermal expansion, and surfaces that won't bond without treatment.

Properties

Mechanical
Mechanical properties for HDPE
Tensile24–32 MPa (3,500–4,600 psi) — unfilled grades; glass-filled grades reach 60–80 MPa
Yield22–30 MPa (3,200–4,400 psi) — HDPE yields with a clear yield point
Elongation100–1000% (highly grade-dependent; pipe-grade and molding grades 600–1000%, sheet grades 100–500%)
Modulus0.8–1.4 GPa (115,000–200,000 psi) — about 2× LDPE, half of POM
Flexural28–38 MPa (4,100–5,500 psi)
Compressive20–25 MPa (2,900–3,600 psi) at 1% deflection
HardnessShore D 65–70 / Rockwell R 50–70 — softer than POM, harder than LDPE
Izod impact50–260 J/m notched (0.9–4.8 ft·lb/in) — grade-dependent; pipe-grade is tough, sheet grade more brittle
Poisson's ratio0.46
Thermal
Thermal properties for HDPE
Continuous max75–85°C continuous (167–185°F) — softens noticeably above this
Short-term max90–100°C short-term (washdown, sterilization)
Min service-100°C — HDPE retains toughness at cryogenic temperatures
Conductivity0.46–0.52 W/m·K (higher than most plastics — HDPE conducts heat reasonably)
CTE120–200 × 10⁻⁶/°C (67–110 × 10⁻⁶/°F) — very high; major design constraint
Specific heat1900 J/kg·K
Plastic-specific
Crystallinitysemi crystalline
Tg-120 to -100°C — far below ambient; HDPE is tough at all practical service temps
HDT75–90°C at 0.45 MPa / 43–50°C at 1.82 MPa (D648)
UL RTI~80°C (UL RTI, conservative long-term)
Moisture (sat)<0.01–0.1% at saturation (essentially zero)
Water (24hr)<0.01–0.1% (24hr immersion) — among the lowest of any plastic
LOI17%
UL94HB
µ (friction)0.29

Variants (8)

HDPE Sheet (general industrial) sheet
Trade: Polystone G, Densetec, Sanatec

Standard pressed sheet stock for fabrication, machining, and tank construction. Property data above represents this variant.

PE100 / PE4710 Pipe Grade HDPE pipe-PE100
Trade: Marlex HHM, Hostalen CRP

High-molecular-weight bimodal resins engineered for slow crack growth resistance. PE100 is the global pipe standard; PE4710 is the higher- performance PPI grade used in US potable-water and gas distribution.

FDA Cutting Board HDPE cutting-board
Trade: Sanatec, King StarBoard ST, Densetec FDA

FDA-compliant, food-safe sheet for cutting boards and food prep surfaces. Resists hot-water washdown, cleaning chemicals, and bacterial growth in surface texture.

UV-Stabilized Marine HDPE marine-UV
Trade: King StarBoard, Seaboard, TimberLine

Carbon-pigmented or HALS-stabilized HDPE for outdoor marine and recreational use. Multi-year UV lifetime. Often textured for non-skid surfaces (Grip-X, Seaboard surfaces).

Reprocessed / Recycled HDPE reprocessed
Trade: Polystone G Utility Black, Densetec Post-Consumer

Made from reclaimed bottles, containers, and process scrap. Economical for non-food, non-critical industrial applications. Properties slightly lower and more batch-variable than virgin.

Orthotic/Prosthetic HDPE (CMPE-500) O-and-P
Trade: Orthoform, CMPE-500

Higher-molecular-weight, controlled-toughness HDPE for ankle-foot orthoses, knee braces, and prosthetic foot plates. Tougher and stiffer than commodity HDPE; specifically formulated for fatigue life under repeated flexure.

30% Glass-Filled HDPE glass-filled

Structural HDPE grade for industrial parts requiring stiffness. Sacrifices HDPE's signature ductility and ESC resistance.

Antimicrobial HDPE antimicrobial
Trade: King MediGrade, SIMOGUARD HDPE

For healthcare cabinetry, medical carts, locker rooms, and food equipment where surface bacterial growth must be suppressed. Antimicrobial agent integrated at molecular level.

Processing

Machinability: good
Chip: Stringy continuous chips at typical feeds. HDPE does not chip-break cleanly — slow feeds produce ribbons that wrap on tooling, aggressive feeds with sharp tools produce a manageable continuous chip.
Gumming: Low if tooling is sharp. HDPE melts at 130°C — localized friction heat from dull tooling or aggressive cuts without coolant will smear and gum the surface.
Finish: 32 Ra readily; 16 Ra achievable but HDPE's softness limits how meaningful finer finishes are.
Tooling: Sharp HSS or carbide, positive rake, generous relief angles. Speed 500–1500 SFM, feed 0.005–0.020 in/rev. Workholding is the gotcha — HDPE is compliant enough to deflect under aggressive clamping. Distribute pressure or use vacuum tables.
HDPE machines well for a commodity polymer. Heat is the dominant failure mode — flood coolant prevents melting and smearing. Bonding requires plasma, flame, or corona treatment; solvent welding does not work. For permanent joins, thermoplastic hot-air or extrusion welding (the standard method for HDPE tanks) is the production technique. Mechanical fasteners and threaded inserts are the practical alternative.
Process compatibility
injection molding excellent
extrusion excellent
cnc machining good
fdm good
sla dlp not-applicable
sls fair
mjf not-applicable
thermoforming good
blow molding excellent
compression molding excellent

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Additives
glass fiber (20–40%) — Niche grade for structural HDPE parts where stiffness and dimensional stability matter more than HDPE's signature ductility. Used in some injection-molded automotive and industrial components.
uv stabilizer (2–3% carbon black (or HALS package)) — Black HDPE is the de facto outdoor grade — carbon black is itself a UV stabilizer. HALS-stabilized natural and colored grades exist for applications where black is unacceptable (playground equipment, signage, marine).
antistatic carbon (8–15% conductive carbon) — Anti-static HDPE for electronics packaging, explosion-risk environments, and powder-conveying applications.
antimicrobial (proprietary silver-ion or EPA-registered compound) — King MediGrade, SIMOGUARD additive. Used in healthcare cabinetry, cutting boards, and locker rooms. Bonded at molecular level — does not wash off.
metal detectable (proprietary metal-detectable compound) — Blue-colored, metal-detectable HDPE for food and pharma equipment. Standard for cutting boards and wear strips in plants with metal detector quality systems.

Chemical resistance

acids excellent Excellent in dilute and most concentrated acids at room temperature. Concentrated nitric and oxidizing acids attack at elevated temperature.
bases excellent Excellent in all common bases at all concentrations and temperatures.
aliphatic Solvents good Resistant at room temperature; some swelling possible in hot aliphatics. Good in gasoline, diesel, lubricants — major use case in fuel tanks.
aromatic Solvents fair Swells in hot aromatics (xylene, toluene). Stress cracking initiator under load. Avoid sustained exposure above 40°C.
fuels Oils excellent Standard material for fuel tanks (HMW-HDPE blow-molded) and lubricant containers.
hot Water Steam good Excellent in water at any temperature up to HDPE's softening point. Common in hot-washdown food equipment.
alcohols excellent Resistant to most alcohols; some surfactant-grade alcohols can be ESC initiators under load.
HDPE is broadly chemically resistant. The real exposure concern is Environmental Stress Cracking (ESC) — under tensile stress, certain chemistries (surfactants, hot aromatics, some oxidizers) can initiate slow crack growth even when the material would be fine unstressed. For demanding service, specify a high-molecular-weight ESC-resistant grade (PE100, PE4710, or proprietary pipe-grade compounds).
⚠ Stress-cracking agents
Anionic and nonionic surfactants (detergents, wetting agents)Hot aromatic hydrocarbons (xylene, toluene)Concentrated nitric acid at elevated temperatureChromic acid (strong oxidizer)Silicone oils (under high stress)

Regulatory

FDA grade
NSF 51
NSF 61
USP Class VI
RoHS
REACH
EU 10/2011
HB UL94 best

FDA-compliant HDPE grades dominate the cutting board, food-equipment, and water-pipe markets (Sanatec, Densetec PC, pipe-grade resins). NSF/ANSI 61 pipe-grade HDPE is the standard for municipal potable water service. UL94 is HB only — HDPE is flammable and cannot be flame-retardant compounded to V-0 without significantly changing its character. Recycled-content grades (post-consumer Densetec, Polystone G Utility) typically lose FDA compliance.

Notes & applications

Overview

HDPE (high-density polyethylene) is the volume-leading semi-crystalline commodity polymer — the second most-produced plastic globally after PP. It dominates chemical storage tanks, municipal water and gas pipe, cutting boards, marine fabrication, and any application where chemical resistance, near-zero moisture absorption, and easy thermoplastic welding matter more than stiffness or temperature capability.

The selection criteria are clear: good chemical resistance and FDA compliance at low cost, willingness to accept ~80°C service temperature, high CTE, and unbondable surfaces. Step outside those constraints and HDPE is the wrong choice — PP for higher temperature, POM for stiffness and tight tolerances, PEEK or PVDF for chemicals HDPE can’t handle.

The single most important grade distinction is pipe grade vs. sheet grade. PE100 and PE4710 pipe-grade resins are engineered for slow crack growth resistance — they handle decades of internal pressure and surfactant exposure that commodity sheet HDPE would environmental-stress-crack within years. Don’t substitute one for the other.

Machining notes

HDPE machines reasonably well for a commodity polymer. The two consistent gotchas:

  1. Heat is the enemy. HDPE melts at ~130°C. Aggressive cuts without coolant generate enough localized friction heat to smear, gum, and melt the surface. Flood coolant or generous chip clearance solves it.
  2. Workholding deflects parts. HDPE is compliant enough that clamping pressure distorts thin sections. Vacuum tables, fixture jigs, or distributed clamping are standard for sheet machining.

Practical recipe:

  • Sharp HSS or carbide, positive rake, generous relief angles
  • Speed: 500–1500 SFM
  • Feed: 0.005–0.020 in/rev — slower feeds produce stringy chips
  • Coolant: flood emulsion recommended for production cuts
  • Tool wear is minimal; HDPE doesn’t abrade tooling

Surface finish tops out around 16 Ra — HDPE’s softness means even with sharp tooling and finishing passes, the surface is easily marred under contact pressure.

For HDPE tanks and fabricated assemblies, the production joining method is thermoplastic welding — hot-air, extrusion, or butt-fusion welding using HDPE rod or filler. Done correctly, the weld develops 80–100% of parent material strength. Adhesive bonding requires plasma, flame, or corona treatment first.

Variant selection guidance

  • Sheet HDPE (Polystone G, Densetec) — the default for tanks, fabrication, machining, and general use. FDA grades for food contact.
  • Pipe grade (PE100, PE4710) — for any pressurized fluid service, buried pipe, or surfactant exposure. Engineered for ESC resistance and 50-year hydrostatic design life.
  • Cutting board (Sanatec, King StarBoard ST) — FDA, NSF 51, designed for repeated knife contact and hot-water washdown.
  • Marine UV (King StarBoard, Seaboard) — outdoor use with carbon or HALS UV stabilization. Often textured for non-skid surfaces.
  • Reprocessed (Polystone G Utility, Densetec PC) — non-critical industrial applications where cost is the driver. Not FDA.
  • O&P (Orthoform, CMPE-500) — controlled-toughness HDPE for orthotics and prosthetics with specified fatigue performance.
  • Antimicrobial (King MediGrade) — healthcare and food environments where bacterial growth on surfaces is a concern.

Failure modes worth designing around

Environmental Stress Cracking (ESC) is the signature HDPE failure mode. Under sustained tensile stress, certain chemistries — surfactants are the big one — cause slow crack growth in HDPE that would never fracture in clean service. Detergent solutions, soap, some alcohols, and silicone oils are all documented ESC initiators. The standard test is ASTM D1693 (bent strip ESC). For service in wash environments, pipe-grade ESC-resistant resin is mandatory.

Creep is the second design issue. HDPE cold-flows under sustained load even at room temperature. Bolted joints lose preload over months; gasket seals relax. Either accept the deformation, use spring preload, or pick a stiffer material.

Thermal expansion — at 120–200 × 10⁻⁶/°C, HDPE has CTE roughly 10× steel. A 6 m HDPE pipe run sees ~50 mm of length change over a 40°C temperature swing. Pipe systems use expansion loops; rigid mounts to steel or concrete fail.

Softening above 80°C is the real continuous-service limit. HDPE loses half its stiffness by 90°C and most of it by 110°C. For 100°C continuous service, PP is the next polyolefin step up.

UV degradation of natural HDPE is fast — 6–18 months of outdoor exposure causes yellowing and surface embrittlement. Carbon black at ≥2% loading is the gold-standard UV stabilizer and the reason most outdoor HDPE is black.

Bonding doesn’t work without surface activation. Plasma, flame, or corona treatment activates the surface for adhesives. Mechanical fasteners, thermoplastic welding, or designed-in mechanical joints are the production methods.

Applications by industry

  • Chemical and process — storage tanks, drums, secondary containment liners, pipe and fittings. HDPE’s chemical resistance and weldability make it the default for non-aggressive chemistries below 80°C.
  • Water and wastewater utilities — pipe-grade HDPE (PE100/PE4710) dominates new municipal water main, gas distribution, and trenchless installations. Heat-fusion-welded for permanent leak-free joints.
  • Food and beverage — cutting boards, conveyor wear strips, hopper liners, food-equipment components. FDA grades widely available.
  • Marine — dock boxes, hatch covers, anti-skid walkways, fender pads, transom mounts. King StarBoard is the category-defining brand.
  • Mining and material handling — truck bed liners, hopper liners, chute liners. HDPE replaces UHMW where stiffness matters more than ultimate impact resistance.
  • Medical (non-implant) — O&P (ankle-foot orthoses, prosthetic components), surgical instrument handles, antimicrobial cabinetry.
  • Construction and outdoor — playground equipment, outdoor furniture, signage, geomembrane liners for landfill and water containment.
  • Packaging — blow-molded bottles, fuel tanks, drums, IBC containers. HMW-HDPE handles the larger formats.

Sources & standards

Standards: ASTM D3350 (Polyethylene pipe materials)ASTM D1248 (Polyethylene plastics molding and extrusion materials)ISO 17855 (Polyethylene molding and extrusion materials)FDA 21 CFR 177.1520 (polyolefin food contact)NSF/ANSI 51 (food equipment materials)NSF/ANSI 61 (potable water — pipe grades)3-A Sanitary (dairy and food processing)

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