All metals

Titanium Grade 9 (Ti-3Al-2.5V)

Titanium $$$

Near-alpha titanium alloy — sometimes called "half-6-4" because it contains half the Al and V content of Grade 5. Cold-formable (unlike Grade 5), weldable, with 20–50% higher strength than CP Grade 2 at moderate cost premium. The standard alloy for aerospace hydraulic and fuel tubing (the application that drove its development at TIMET in the 1970s), and for premium bicycle frames where weldability + cold formability matter. ASTM B338 covers seamless and welded tubing; AMS 4943/4944/4945 cover aerospace hydraulic tubing in annealed and CWSR conditions.

Service °C
~315°C (600°F) continuous; usable up to ~427°C short-term with reduced strength
Tensile
620 MPa min annealed (90 ksi) per ASTM B338; 860 MPa min CWSR (125 ksi)
Density
4.48 g/cm³ (0.162 lb/in³) — between CP Ti and Grade 5
Cost
$$$
$22.00/lb
Trade names: Ti-3-2.5Ti-3Al-2.5VASTM Grade 93.7195 (DIN)Alleima Ti Grade 9Half 6-4 (informal)

Near-alpha titanium alloy — sometimes called "half-6-4" because it contains half the Al and V content of Grade 5. Cold-formable (unlike Grade 5), weldable, with 20–50% higher strength than CP Grade 2 at moderate cost premium. The standard alloy for aerospace hydraulic and fuel tubing (the application that drove its development at TIMET in the 1970s), and for premium bicycle frames where weldability + cold formability matter. ASTM B338 covers seamless and welded tubing; AMS 4943/4944/4945 cover aerospace hydraulic tubing in annealed and CWSR conditions.

Properties

Mechanical
Mechanical properties for Titanium Grade 9 (Ti-3Al-2.5V)
Tensile620 MPa min annealed (90 ksi) per ASTM B338; 860 MPa min CWSR (125 ksi)
Yield483 MPa min annealed (70 ksi); 725 MPa min CWSR (105 ksi)
Elongation15% min annealed per ASTM B338; 10% min CWSR; typical 18–22% in annealed bar
Modulus100–107 GPa (14,500–15,500 ksi)
HardnessRockwell C 22–28 typical
Fatigue strength~50% of UTS endurance limit (10⁷ cycles); 380–480 MPa typical with controlled crystal texture
Poisson's ratio0.3
Thermal
Thermal properties for Titanium Grade 9 (Ti-3Al-2.5V)
Continuous max~315°C (600°F) continuous; usable up to ~427°C short-term with reduced strength
Short-term max427°C (800°F) short-term; alpha-case formation above 540°C in air
Min service-253°C — cryogenic capable
Conductivity7.6 W/m·K — similar to Grade 5, lower than CP Ti
CTE7.9 × 10⁻⁶/°C (4.4 × 10⁻⁶/°F) — very low expansion, useful for tight-tolerance hydraulic systems
Specific heat427 J/(kg·K)
Metal-specific
UNSR56320
EN3.7195
Magneticnon magnetic
Cond.1.4% IACS
Composition (% wt)
Ti balance Al 2.5–3.5 V 2.0–3.0 Fe ≤0.25 (≤0.30 per ASTM) O ≤0.12 (≤0.15 per ASTM) C ≤0.05 (≤0.08 per ASTM) N ≤0.02 (≤0.03 per ASTM) H ≤0.015 other_each ≤0.10 other_total ≤0.40

Variants (4)

Ti-3Al-2.5V Annealed (AMS 4943) grade9-annealed

Standard supply condition. ASTM B338 mins: 620 MPa UTS / 483 MPa yield / 15% elongation. Best ductility and cold formability. Property data above reflects this state.

Ti-3Al-2.5V CWSR (AMS 4944 / 4945) grade9-cwsr Cold Worked Stress Relieved

High-strength tubing for aerospace hydraulic systems. AMS 4944 is the standard CWSR spec; AMS 4945 covers higher-strength variants. The dominant supplied form for aerospace hydraulic and fuel lines.

Ti-3Al-2.5V Medical (ASTM F1295) grade9-medical

Same chemistry, tight melt and inclusion control for implantable medical device use. Less common than Grade 23 ELI but used in specific applications where the cold formability of Grade 9 matters (some catheter and surgical guide hardware).

Ti-3Al-2.5V Bicycle Tubing (proprietary) grade9-bicycle-tube

Seamless or welded-and-drawn tubing in custom diameter/wall combinations for bicycle frame builders. Often supplied in annealed temper for weldability; CWSR for some butted-tube designs. Manufacturers (Reynolds, Columbus, Sandvik/Alleima) supply proprietary tube sets.

Processing

Machinability: fair
Chip: Between CP Ti and Grade 5 — tougher chips than CP, less work-hardening than Grade 5. Similar precautions to other Ti grades.
Gumming: Significant. Low thermal conductivity concentrates heat at tool edge. Flood coolant required.
Finish: 32–63 Ra typical for production work; 16 Ra possible with finishing. Wall thickness consistency more critical for tubing than surface finish.
Tooling: Sharp uncoated or polished-edge carbide. Speed 40–70 SFM annealed, 25–50 SFM CWSR. Feed 0.004–0.012 in/rev. Flood coolant; no chlorinated fluids. Most Grade 9 product is tubing — machining is mainly limited to fittings, manifolds, and end-form operations.
Grade 9 is most often supplied as tubing rather than bar/plate, so typical "machining" is flaring, swaging, bending, and end-prep rather than bulk material removal. For the bar/plate that exists, machining is incrementally easier than Grade 5 due to lower strength, but the fundamental Ti machining rules apply: slow speeds, flood coolant, no dwelling, wet chip collection. Tube bending (cold) is a key Grade 9 operation and requires mandrels for tight-radius bends.
Weldability: excellent

Grade 9 is one of the most weldable titanium alloys — better than Grade 5, comparable to CP Ti. The lower Al+V content means less martensite formation in the HAZ and reduced alpha-case sensitivity. Same fundamental requirement: full inert-gas shielding for everything above ~400°C. TIG with argon shielding is standard. Trail shield and back-purge mandatory. CWSR tubing welded with autogenous (no filler) orbital TIG retains ~90% of parent UTS — excellent for hydraulic system fabrication. ERTi-9 filler matches the chemistry; ERTi-2 (CP) filler is sometimes used where corrosion resistance matters more than matching strength. No PWHT typically required, though stress relief anneal (540–650°C / argon) restores some ductility in heavily welded assemblies.

Heat treatments
Mill Anneal (Rockwell C 22–28) — Default supply condition. Restores ductility after cold work. Used as the starting temper for cold drawing tubing.
Cold Worked + Stress Relieved (CWSR) — The high-strength condition for hydraulic tubing per AMS 4944/4945. Combines cold-work strengthening with stress relief that preserves most of the strength gain while restoring some ductility. Aerospace hydraulic tubing is typically supplied CWSR for the strength-to- weight benefit at 5000–8000 psi system pressures.
Stress Relief — Below recrystallization. Used after severe forming or welding to relieve stress without changing properties.
Vacuum Anneal — Used for medical and aerospace finished parts where surface contamination during anneal is unacceptable.
Surface treatments
Anodic oxide (interference color) (<1 μm) — Decorative coloring. Common on premium Grade 9 bicycle frames for anodized accents and on aerospace tubing for fluid-system color coding (hydraulic vs fuel vs pneumatic identification).
Passivation (HNO₃ or citric) (<10 nm) — Standard post-fabrication treatment. Critical for medical and high-purity hydraulic service.
Nitriding (1–25 μm) — Used on Grade 9 fittings and threaded interfaces to eliminate galling. Less common on tubing than on bar/fittings.
Electropolishing — Standard finish for medical-grade Grade 9 tubing and high-purity hydraulic systems. Smoothes ID and OD, removes inclusion residue from cold drawing.

Corrosion resistance

general Atmospheric excellent Same TiO₂ passive film as CP Ti — essentially immune.
saltwater excellent Excellent in seawater. Slightly more vulnerable than CP Grade 2 to crevice corrosion in hot brines, but better than Grade 5 due to lower Al+V content.
acids good Same as CP Ti — excellent in oxidizing, poor in reducing acids, fail in HF.
bases excellent
oxidizing Environments excellent
reducing Environments fair
Galvanic position essentially identical to CP Ti and Grade 5 — very noble. Isolate from less-noble metals in marine and chemical service. The lower Al content (3% vs Grade 5's 6%) makes Grade 9 slightly better in crevice corrosion environments where the Al-rich alpha phase in Grade 5 can act as preferential corrosion site.
⚠ Galvanic risks with
Aluminum (Ti cathodic — Al corrodes)Carbon steelZinc / galvanizedMagnesium

Regulatory

FDA grade
NSF 51
NSF 61
USP Class VI
RoHS
REACH
EU 10/2011

Approved for ASME Boiler and Pressure Vessel Code Section VIII Div 1 Case 2081. Used in some implantable medical devices, though Grade 23 ELI dominates the implant market. RoHS and REACH compliant.

Notes & applications

Overview

Grade 9 (Ti-3Al-2.5V) is the alloy that solves a specific problem: you need higher strength than CP Grade 2 but you can’t give up cold formability or weldability the way Grade 5 makes you. The half-aluminum, half-vanadium composition (versus Grade 5’s 6Al-4V) keeps the alloy in the near-alpha regime where the HCP slip restrictions of pure titanium are relaxed enough to permit cold drawing, cold tube bending, and clean welding.

The application that drove Grade 9’s development at TIMET in the 1970s was aerospace hydraulic tubing. Modern hydraulic systems operate at 5000–8000 psi; stainless steel tubing at those pressures gets heavy, and Grade 5 can’t be cold drawn to the tight diameter tolerances needed. Grade 9 splits the difference: ~125 ksi UTS in CWSR temper at 4.48 g/cm³ (roughly 45% lighter than steel tubing), drawn and stress-relieved to aerospace tolerances, with fatigue performance and bend radius characteristics that work for routed aircraft systems.

Beyond hydraulics, Grade 9 has found a niche in premium bicycle frames (welded seamless tubing — Litespeed, Lynskey, Moots, Seven Cycles, Sage Titanium, Eriksen, and many others), specific oil-and-gas sour- service applications, and high-end sporting goods. Wherever you need titanium’s corrosion and strength-to-weight with welded tube construction, Grade 9 is the alloy.

Why Grade 9 vs Grade 2 vs Grade 5

Selection logic for titanium grade in tubular applications:

Property Grade 2 (CP) Grade 9 Grade 5
UTS (annealed) 345 MPa min 620 MPa min 895 MPa min
UTS (max temper) ~550 (CW) 860 MPa (CWSR) 1170 MPa (STA)
Cold formable excellent good very limited
Weldable excellent excellent good
Cost $$$ $$$ $$$
Density 4.51 4.48 4.43

Pick Grade 2 when CP corrosion is the priority and strength is secondary (chemical processing, low-pressure marine hardware). Pick Grade 9 when you need higher strength + welded tube construction. Pick Grade 5 when you need maximum strength and you can hot-form or machine the part to shape.

For aerospace hydraulic tubing specifically, Grade 9 has no real competitor at the cost-performance balance. Stainless is heavy, Inconel is heavier and more expensive, and Grade 5 can’t be cold-drawn to the required tolerances.

Welding and tube fabrication

Grade 9’s weldability is the property that distinguishes it from Grade 5 in tubular applications. Autogenous orbital TIG welding of Grade 9 hydraulic tubing — no filler, just fusion of the parent material — retains roughly 90% of CWSR parent UTS in the weld zone with proper shielding. This is the manufacturing basis for welded aerospace hydraulic lines and welded bicycle frames.

Practical requirements (same as all Ti):

  • TIG with argon shielding, trail shield, back-purge inside tubing
  • Cleanliness absolute — stainless brush dedicated to Ti, acetone or MEK degrease, no chlorinated solvents
  • ERTi-9 filler when needed (most Grade 9 tube welds run autogenous)
  • ERTi-2 (CP) filler sometimes used for high-purity / corrosion service

Bicycle frame welding is a craft skill — orbital welding or skilled manual TIG with multi-pass technique for thicker joints. Premium frame builders use heat-controlled welding procedures to minimize distortion and HAZ degradation.

Tube bending is a separate skill set:

  • Annealed Grade 9: 3D bend radius minimum cold; tighter with mandrel and lubricant
  • CWSR Grade 9: 5D bend radius minimum; tighter bends require intermediate anneal or warm forming

Machining notes

Most Grade 9 product is tubing rather than bar, so typical “machining” is flaring, swaging, end-forming, and fitting operations rather than bulk material removal. For the bar and plate that exists, machining is fundamentally similar to other Ti grades:

  • Speed 40–70 SFM annealed, 25–50 SFM CWSR
  • Feed 0.004–0.012 in/rev
  • Sharp polished-edge carbide, generous rake
  • Flood coolant (never chlorinated), high-pressure preferred
  • No dwelling
  • Wet chip collection (pyrophoric hazard)
  • Soft-jaw or low-pressure clamping (low modulus, deflects)

Tube end-forming (flaring, sleeve attachment, swaging) is a specialized skill for hydraulic system fabrication. AS-style flares per AS33514 are the dominant aerospace fitting standard.

Cold formability — the defining property

Grade 9 can be cold worked 75–85% reduction in area from annealed temper while retaining sufficient ductility for further processing. This enables several manufacturing operations that aren’t practical on Grade 5:

  • Cold drawing tubing — multi-pass cold draw through diamond/carbide dies to tight diameter tolerances without intermediate anneals
  • Pilgering — cold rolling of seamless tube hollow over a mandrel, with reduction ratios up to 30:1 per pass
  • Cold tube bending — formed to complex routing without heating
  • Cold heading — for fasteners and small forged shapes
  • Sheet metal forming — bending, drawing, and stretch forming at room temperature

The trade-off versus CP Ti is reduced ductility — Grade 9 is harder to form than CP Grade 2 but harder to work-harden (anneal-resistant), so it tolerates moderate forming without becoming brittle.

Applications by industry

  • Aerospace — the dominant Grade 9 application is aerospace hydraulic and fuel tubing. F-22, F-35, 787, A350 hydraulic systems use Grade 9 CWSR tubing per AMS 4944/4945. The Boeing 787 alone uses ~3000 lb of Grade 9 hydraulic tubing per airframe.
  • Premium bicycles — welded Grade 9 frame tubing. Established builders (Litespeed, Lynskey, Moots, Seven, Sage, Eriksen) use Grade 9 tubing in proprietary diameter/wall combinations. The “titanium bike” market is essentially Grade 9 (with some Grade 5 for very high-strength applications).
  • Sporting goods — premium lacrosse heads, tennis racquet frames, walking sticks, ski poles. Specialty market.
  • Oil and gas — sour-service tubing per NACE MR0175 in some applications where Grade 9’s combination of strength and corrosion resistance fits the service profile.
  • Heat exchangers — high-pressure aggressive-fluid heat exchanger tubing where CP Ti’s strength is inadequate.
  • Medical — specific catheter and surgical guide tubing applications where Grade 9’s cold formability matters and full implant qualification isn’t required.

Failure modes worth designing around

Galling — universal Ti issue. Surface-treat sliding contact.

Hot-salt SCC above ~290°C from chloride contamination, same as Grade 5. Chloride-free cleaning required.

Hydrogen embrittlement from acid pickling residue or galvanic over-protection.

Alpha-case formation during high-temperature exposure in air.

Tube forming cracks if cold-formed beyond temper limits — CWSR tubing has reduced cold-form capability vs annealed. Spec the right temper for the forming operation.

Weld zone fatigue — welded Grade 9 tube weld zone has ~90% of parent UTS but reduced fatigue strength. Design hydraulic systems with weld zones in low-stress locations where possible.

Methanol SCC — same as other Ti grades.

Pyrophoric chip hazard during machining — wet collection, Class D fire suppression on hand.

Variant selection

  • Annealed (AMS 4943) — cold-form, weld, then put in service. Best ductility and formability; use when post-processing matters.
  • CWSR (AMS 4944 / 4945) — high-strength tubing for aerospace hydraulic and fuel systems. Reduced cold formability; design with generous bend radii.
  • Medical (ASTM F1295) — implant-grade chemistry control; specific catheter applications.
  • Bicycle tubing — proprietary supplier specs; annealed temper is dominant for frame builder welding.

Sources & standards

Standards: ASTM B265 Grade 9 (sheet, strip, plate)ASTM B337 Grade 9 (seamless and welded pipe — superseded by B861/B862)ASTM B338 Grade 9 (seamless and welded tubing — heat exchangers)ASTM B348 Grade 9 (bar and billet)ASTM B381 Grade 9 (forgings)ASTM F1295 (alpha-beta Ti alloy for medical implant — Grade 9 family)ASME SB-338 (pressure vessel tubing, Boiler Code Case 2081)AMS 4943 (hydraulic tubing, annealed)AMS 4944 (hydraulic tubing, CWSR, 90 ksi class)AMS 4945 (hydraulic tubing, CWSR, 125 ksi class)AMS 4989 (sheet, strip, plate)ABS 5004 / ABS 5141 (aerospace specifications)DIN 3.7195EN Ti Grade 9 (3Al/2.5V)NACE MR0175 (sour service)

Related titanium materials