All plastics

POM (Acetal)

Engineering $$

Polyoxymethylene. The workhorse engineering thermoplastic for precision mechanical parts — gears, bearings, fittings, manifolds. Combines high stiffness, low friction, excellent machinability, low moisture absorption, and good dimensional stability. Available as homopolymer (Delrin, higher strength) or copolymer (Hostaform/Acetron, better hot-water and chemical resistance). The default plastic when a part needs tight tolerances and predictable in-service behavior.

Service °C
85–95°C continuous (185–205°F); copolymer ~10°C higher than homo
Tensile
65–70 MPa (9,400–10,000 psi)
Density
1.41–1.42 g/cm³ (0.051 lb/in³)
Cost
$$
$3.20/lb
Trade names: Delrin (DuPont/Celanese homopolymer)Hostaform (Celanese copolymer)Acetron (Mitsubishi/Quadrant copolymer)Sustarin (Röchling)TECAFORM (Ensinger)Celcon (Celanese copolymer, legacy)Ultraform (BASF copolymer)

Polyoxymethylene. The workhorse engineering thermoplastic for precision mechanical parts — gears, bearings, fittings, manifolds. Combines high stiffness, low friction, excellent machinability, low moisture absorption, and good dimensional stability. Available as homopolymer (Delrin, higher strength) or copolymer (Hostaform/Acetron, better hot-water and chemical resistance). The default plastic when a part needs tight tolerances and predictable in-service behavior.

Properties

Mechanical
Mechanical properties for POM (Acetal)
Tensile65–70 MPa (9,400–10,000 psi)
Yield65–70 MPa (homopolymer slightly higher than copolymer)
Elongation10–75% (highly grade- and section-dependent; filled grades 10–15%, unfilled thin sections up to 75%)
Modulus2.8–3.1 GPa (410–450 ksi)
Flexural90–100 MPa (13,000–14,500 psi)
Compressive108–124 MPa (15,700–18,000 psi)
HardnessShore D 83 / Rockwell M 80–89 / Rockwell R 118–121
Izod impact53–80 J/m notched (1.0–1.5 ft·lb/in)
Fatigue strength24–31 MPa at 10⁷ cycles
Poisson's ratio0.35
Thermal
Thermal properties for POM (Acetal)
Continuous max85–95°C continuous (185–205°F); copolymer ~10°C higher than homo
Min service-50°C (-58°F)
Conductivity0.23 W/m·K
CTE110–122 × 10⁻⁶/°C (61–68 × 10⁻⁶/°F) — high; design for thermal cycling
Specific heat1300 J/kg·K
Plastic-specific
Crystallinitysemi crystalline
Tg-60 to -50°C (below room temperature — POM is leathery-tough at ambient)
HDT110–125°C at 1.82 MPa / 158–169°C at 0.45 MPa (D648)
UL RTI~85°C (UL RTI, conservative long-term)
Moisture (sat)0.8–1.0% at saturation (much lower than nylon)
Water (24hr)0.20–0.25% (24hr immersion)
LOI15%
UL94HB
µ (friction)0.21

Variants (5)

POM-H Homopolymer (Delrin) POM-H
Trade: Delrin, Delrin 150, Delrin 511P

Higher mechanical properties, lower porosity in thin sections than copolymer. Brittle in hot water and especially hot chlorinated water — choose POM-C for those environments. Delrin is essentially synonymous with POM-H.

POM-C Copolymer (Hostaform / Acetron / TECAFORM AH) POM-C
Trade: Hostaform, Acetron, TECAFORM AH, Sustarin, Celcon

Slightly lower mechanicals than POM-H, but significantly better resistance to hot water, hot caustic, and long-term thermal aging. FDA-compliant grades are easier to source. Copolymer is the right default for food, fluid handling, and automotive fuel systems.

20% Glass-Filled POM-H (Delrin 570) GF20
Trade: Delrin 570

Higher stiffness for structural gear/bearing applications. Sacrifices impact and tensile for flex modulus. Not FDA.

PTFE-Filled POM (TECAFORM HPV13 / Delrin AF) HPV13
Trade: TECAFORM AH HPV13, Delrin AF, Delrin AF DE588

Bearing and bushing grade with much lower friction (CoF ~0.12) and superior wear life. Delrin AF DE588 specifically meets US Naval Sea Systems Command spec for shipboard mechanical components.

Food/Metal-Detectable POM-C (TECAFORM AH UD blue) FG-MD
Trade: TECAFORM AH UD blue, Sanalite-PE-MD (similar concept)

Food-industry standard for components that could fragment into product stream. Blue color is the visual flag, metal-detectable compound is the safety net.

Processing

Machinability: excellent
Chip: Forms short to medium chips with sharp tooling — among the best-machining thermoplastics. Chip breakers usually unnecessary at typical feeds.
Gumming: Very low. POM machines cleaner than any other engineering plastic. Coolant optional for light cuts; recommended for heavy machining to control heat in the part.
Finish: 16 Ra readily; 8 Ra with finishing passes. Diamond-turned POM is used for precision optical and mechanical surfaces.
Tooling: Sharp carbide or HSS, positive rake, polished cutting edges. Run at 500–1500 SFM. Feed 0.005–0.015 in/rev typical. Watch for heat buildup on thick sections — POM has high thermal expansion and will move if heated unevenly during machining.
Stress-relief anneal at 120–160°C for 1 hr/inch of section thickness after heavy machining if dimensional stability is critical. Bonding requires surface activation (plasma, flame, or chromic acid etch); mechanical fasteners and snap fits are the standard joining methods. Solvent welding does not work. Ultrasonic welding is possible but not common.
Process compatibility
injection molding excellent
extrusion excellent
cnc machining excellent
fdm poor
sla dlp not-applicable
sls fair
mjf not-applicable
thermoforming poor
blow molding fair
compression molding good

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Additives
glass fiber (20–30%) — Less common in POM than in nylon — POM's polymer chemistry doesn't bond as well to glass fibers as nylon's does, so the strength gain is modest while ductility loss is real. Delrin 570 is the canonical 20% GF grade.
ptfe lubricant (10–20%) — TECAFORM HPV13, Delrin AF, Delrin AF DE588 (military-spec). Self-lubricating bearing grade — best when sliding against steel with minimal lubrication. Mil-spec DE588 is widely used in US Naval applications.
mineral filler (10–20%) — Less common but used in cost-sensitive consumer parts and where isotropic dimensional control matters more than stiffness.
antistatic carbon (5–10% conductive carbon) — TECAFORM AH ELS, Sustarin H ESD. For electronics handling, explosion-risk environments, and where static charges damage product or attract contamination.
metal detectable (proprietary metal-detectable compound) — TECAFORM AH UD blue, food-industry standard for parts that could fragment into a product stream. FDA-compliant.

Chemical resistance

acids poor Strong acids attack POM. Mild acids OK at room temp; avoid sustained acid exposure. This is POM's biggest chemical weakness.
bases fair OK at room temperature in dilute bases. Strong/hot caustic causes chain scission and embrittlement.
aliphatic Solvents excellent Excellent in hydrocarbons, fuels, oils.
aromatic Solvents good Generally resistant; some swelling possible in concentrated.
fuels Oils excellent One of POM's selling points — excellent in gasoline, diesel, lubricants. Copolymer (POM-C) is the automotive fuel-system standard.
hot Water Steam fair POM-C handles continuous hot water to ~80°C reasonably. POM-H embrittles in hot water and especially chlorinated hot water over time. Pick POM-C for any hot-water service.
alcohols excellent
POM's chemical resistance is excellent in non-aqueous and neutral environments. The acid weakness and the POM-H hot-water issue are the two field-failure traps to design around.
⚠ Stress-cracking agents
Strong acids (HCl, H₂SO₄, HNO₃)Hot caustic (>60°C NaOH/KOH)Chlorinated water (POM-H specifically)

Regulatory

FDA grade
NSF 51
NSF 61
USP Class VI
RoHS
REACH
EU 10/2011
HB UL94 best

FDA-compliant copolymer grades are widely available (e.g. food-grade blue Acetron, Delrin 511P, TECAFORM AH FG). Homopolymer FDA compliance is more limited. UL94 rating is HB only — POM is highly flammable and cannot be flame retardant compounded to V-0 without changing its fundamental character. Do not specify for fire-critical applications.

Notes & applications

Overview

POM (polyoxymethylene, commonly called acetal) is the engineering plastic that comes closest to behaving like a soft metal. High stiffness, low friction, predictable dimensional behavior, and the cleanest machining characteristics of any commercial thermoplastic. When a designer needs a plastic gear, bushing, fluid fitting, or precision mechanical part — POM is the default specification.

The biggest single design decision with POM is homopolymer (POM-H, Delrin) versus copolymer (POM-C, Hostaform/Acetron). They look and machine similarly, with property differences typically within 15%. But they fail differently:

  • POM-H has slightly higher strength, stiffness, and creep resistance. It also has tendency toward centerline porosity in thick extruded sections and degrades in hot water and chlorinated environments.
  • POM-C has slightly lower mechanicals but dramatically better long-term resistance to hot water, hot caustic, and thermal cycling. Cleaner porosity in stock shapes.

Default to POM-C for general use unless the application specifically benefits from POM-H’s higher stiffness AND won’t see hot water or strong base exposure.

Machining notes

POM machines like a dream — short clean chips, low gumming, holds tight tolerances without the surface smear or built-up edge issues of softer plastics. Many designers benchmark plastic machinability against POM.

Practical recipe for turning POM bar:

  • Sharp carbide or polished HSS, positive rake
  • Speed: 500–1500 SFM
  • Feed: 0.005–0.015 in/rev
  • Coolant: optional for light cuts, recommended for heavy
  • Polished cutting edges critical for finish

The one thing to watch is heat-induced dimensional drift. POM has high CTE (~110 µm/m·°C, 2× aluminum) and a relatively low maximum service temperature. Uneven heating during heavy machining can warp parts after they cool. For tight-tolerance work on thick sections, either keep cuts shallow with coolant or stress-relieve anneal at 120–160°C for 1 hour per inch of section thickness after roughing.

POM does not bond well. Solvent welding doesn’t work — POM is too chemically inert. Adhesives require surface activation (plasma, flame, or chromic acid etch). Most assembled POM parts use mechanical fasteners, threaded inserts, or snap-fits — POM’s stiffness and fatigue behavior make it one of the best plastics for living hinges and snap features.

Variant selection guidance

  • POM-H (Delrin) — pick when stiffness, creep resistance, or thin-section porosity matters and the part won’t see hot water or strong base. The classic “Delrin gear” application.
  • POM-C (Hostaform/Acetron/TECAFORM AH) — the default. Pick for general engineering use, food-contact applications, automotive fuel systems, and any environment with thermal cycling or moisture.
  • GF20 (Delrin 570) — pick when stiffness is the priority and impact resistance is acceptable. Structural gears under load.
  • HPV13 / Delrin AF — pick for self-lubricating bearings and bushings. Delrin AF DE588 if you need the US Naval Sea Systems Command spec.
  • FG metal-detectable — pick for food and pharma where fragments must be detectable in product streams.

Failure modes worth designing around

Acid attack is the biggest field failure mode. POM degrades in acidic environments through chain scission of the C-O backbone. Mild acids at room temperature are OK; sustained or hot acid contact will embrittle and crack POM parts. If acid exposure is even a possibility, PVDF, PP, or PEEK are better choices.

Hot-water embrittlement of POM-H is the second common failure. Delrin in continuous hot water (>60°C) or chlorinated water (pool, potable treatment) develops surface crazing and loses elongation over months to years. POM-C is dramatically better in this service.

Thermal decomposition during processing or fire produces formaldehyde, which is toxic and irritating. Stay within processing-temperature windows in injection molding (195–215°C melt), and never specify POM for fire-rated applications — it cannot achieve UL94 V-0.

Mold shrinkage is high (2.0–2.5%) and uneven on filled grades. Design with this in mind on tight-tolerance molded parts; machining from stock avoids the issue but the stock itself can have residual quench stresses (especially in thick extruded bar). Stress-relief anneal on critical parts.

Bonding doesn’t work without surface activation. Designers who assume “I’ll just glue it on” find out the hard way. Plan for mechanical fasteners from the start, or budget time for plasma/etch preparation.

Applications by industry

  • General mechanical — gears, bushings, sprockets, wear pads, thrust washers. The default plastic for precision moving parts.
  • Food and beverage — conveyor components, valve bodies, fittings, metering parts. POM-C with FDA grades dominates this space; metal- detectable variants are standard for parts that might fragment.
  • Automotive — fuel system components (POM-C is OEM-standard for fuel rails, pumps, sender modules), seatbelt mechanisms, latches, HVAC valves.
  • Plumbing and fluid handling — manifolds, fittings, pump impellers for non-acid fluids. POM-C for hot-water systems.
  • Consumer products — zippers (widely used alongside PA — POM dominates the heavy-duty and outdoor segments), fasteners, locks, snap-fit hardware, lighter mechanisms.
  • Industrial automation — guides, wear strips, sprockets, cam followers in conveyor and packaging machinery.
  • Medical (non-implant) — surgical instrument handles, drug-delivery device components, valve bodies. Not USP Class VI — for implant use, PEEK is the go-to.

Sources & standards

Standards: ASTM D4181 (POM molding compounds)ISO 9988-1 (POM)ASTM D6100 (POM standard specification)FDA 21 CFR 177.2470 (POM-C food contact)FDA 21 CFR 177.2480 (POM-H food contact)NSF/ANSI 51 (food equipment materials)NSF/ANSI 61 (potable water — select grades)

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